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This second, completely updated edition of a classic textbook provides a concise introduction to the fundamental principles of modern electrochemistry, with an emphasis on applications in energy technology. The renowned and experienced scientist authors present the material in a didactically skilful and lucid manner. They cover the physical-chemical fundamentals as well as such modern methods of investigation as spectroelectrochemistry and mass spectrometry, electrochemical analysis and production methods, as well as fuel cells and micro- and nanotechnology. The result is a must-have for advanced chemistry students as well as those studying chemical engineering, materials science and physics. Batteries, fuel cells, corrosion and electricity - with the advent of materials science and nanotechnology, electrochemistry is more important than ever. It is also becoming increasingly interdisciplinary, such that electrochemistry is a must for all chemistry students in their courses and for laboratory courses in physical chemistry.

This second, completely updated edition of a classic textbook provides a concise introduction to modern electrochemistry, from the physical-chemical fundamentals right up to technical applications, with an emphasis on energy technology. The renowned and experienced textbook authors present the material in a didactically skilful and lucid manner, backed by numerous informative illustrations and tables. The scope of this book covers such modern methods of investigation as spectroelectrochemistry and mass spectrometry, electrochemical analysis and production methods, as well as fuel cells and micro- and nanotechnology. The result is required reading for those majoring in chemistry, as well as those studying chemical engineering, materials science and physics. List of Symbols and Units. 1 Foundations, Definitions and Concepts. 1.1 Ions, Electrolytes and the Quantisation of Electrical Charge.

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1.2 Transition from Electronic to Ionic Conductivity in an Electrochemical Cell. 1.3 Electrolysis Cells and Galvanic Cells: The Decomposition Potential and the Concept of EMF. 1.4 Faraday's Laws. 1.5 Systems of Units.

2 Electrical Conductivity and Interionic Interactions. 2.1 Fundamentals.

2.2 Empirical Laws of Electrolyte Conductivity. 2.3 Ionic Mobility and Hittorf Transport. 2.4 The Theory of Electrolyte Conductivity: The Debye-Hu.ckel-Onsager Theory of Dilute Electrolytes. 2.5 The Concept of Activity from the Electrochemical Viewpoint. 2.6 The Properties of Weak Electrolytes. 2.7 The Concept of pH and the Idea of Buffer Solutions.